ࡱ> 461239 RCbjbj9x 5WBl280\T2L4666!!!KKKKKKK$N PLK! !!!K+&66L+&+&+&!66K+&!K+&+&)nHpK6 p2 2#I K$L0LJQa%QK+&22 Model PHB-4 Portable pH Meter Operation Manual Shanghai San-Xin Instrumentation, Inc. 1. Brief Introduction:  Congratulations on your purchased model PHB-4 portable pH meter hereinafter called the meter from Shanghai San-Xin Instrumentation, Inc. pH value as a measurement indication which is measuring acidity and alkalinity for water solution. The solution which pH value =7 is neutral, pH<7 is acidic and the value is smaller, the acidic is stronger; pH>7 is alkaline and the pH value is larger, the alkaline is stronger. It needs to measure pH value in great many fields such as industrial, agriculture, physic, environmental protecting and scientific research etc. There is a microprocessor chip inside the meter and its appearance looks good with easily operation. For notable features read as follows: 1.1.Equipped with 201B-S pH/ATC 3-in-1 combination electrode which used special sensitive membrane formula and structure mode, not only for measuring normal water solution, but also for measuring surface water, river water, tap water, high purified water and acid rain and so on lower ion strength solution that we can not use normal pH electrode for measuring stably, have response quick, stable display, ATC and so on features. 1.2.Three points automatically calibration for double slope which make the meters accuracy much higher and manual temperature compensation. 1.3.Automatic display slope percentage after calibrating. 1.4.Large blue background LCD screen which can show both pH and temperature value at the same time. 1.5.Inside of the chip has two series data of pH buffer solution, can be choose freely. 1.6.Lower power display, power off automatically after 15 minutes. 1.7.! and ! can be switched automatically. 1.8.Packing with special carrying case and there are standard buffer solution inside it. 2. Technical Parameter:  2.1. Measuring Range: pH: 0~14.00 pH mV: 1999 mV 2.2. Resolution: pH: 0.01pH mV: 1 mV 2.3. Accuracy: pH: meterd"0.01pH 1 digit meter comes with electroded"0.02pH 1 digit mV: d"0.1%F.S 1 digit 2.4. Input Resistance: e"11012 2.5. Temperature Compensation Range: 0~80!(automatic) 2.6. Power: 1pc of model 6F22 9V cell 2.7. Dimension and Weight: 168 x 43 x 26mm/170g 2.8. Working Condition: environment temperature: 5~35!. Relative moisture d"85%RH 3. Meter s Operation:  3.1. pH value measurement: 3.1.1.Short press key to power on. 3.1.2.Taking off the short circuit protecting cap which on the socket of meter, then connect the pH combination electrode, put the electrode into pure water stirring and dry it out. 3.1.3.Fix position calibration: Immerge the pH electrode into pH7.00 buffer solution, still it after slightly stirring and when showed value is stable, then press the calibration button for some minutes, and release it when there showand 7.00 after many seconds, when there display icon, steady pH calibration value and temperature value. (The value at this time will be different during different temperature, for example, meter will display 7.00 when temperature is 25! and it will be 7.04 when temperature is 15!. All of them are setting data inside in the chip) which shows finished calibration and data have been remembered by chip. 3.1.4.Slope`!calibration: Take out electrode, clean it with pure water and dry it out, and insert it into pH4.00 buffer solution, then still it after slightly stirring, and press calibrating button after displayed value become stable. Then release it when there show, first display twinkle 4.00 and after some seconds,symbol, stabled pH calibrating value and temperature value are displayed on the LCD that means calibration is finished and data is remembering by chip. After calibrating, meter will automatically display slope percentage of electrode in this stage. 3.1.5.Slopea!calibration: Take electrode out, wash it with pure water and dry it out, then insert it into pH10.01 buffer solution, still it for almost 10 seconds after slightly stirring, and press calibrating button after displayed value become stable. Then release it when there show, first display twinkle 10.01 and after some seconds,symbol, stabled pH calibrating value and temperature value are displayed on the LCD that means calibration is finished and data is remembering by chip. After calibrating, meter will automatically display slope percentage of electrode in this stage. 3.1.6. Sample measurement: Immerse pH electrode into the sample solution after washing and dry out. Still it after slightly stirring and reading data when it stable display, that is pH value. Note: According to the equal temperature measurement principle for pH testing, the temperature of sample solution is the more closer to standard buffer solutions temperature the measuring value is the much higher, user should pay attention to obey when actual testing. 3.1.7.Specification: There is an intelligent chip in the meter, which could choose one point, two point and three point automatically calibration, it only needs calibrate with pH7.00 buffer solution for one point calibration if the measuring accuracy d"0.1pH. If the measuring range is only in acidic range (pH<7.00) or alkali range (pH>7.00) which could also use two point calibration, except pH7.00 fixed position calibration, you should choose pH4.00 or pH 10.01 for the second point calibration. You should choose three point calibration if the measuring range is wide or pH electrode is aged for has been used for a long time. But when the electrode being used for the first time, it must be calibrated with 3 points to adjust the slope of meter is in accordance with pH electrode. I have helped customers 3.2. Measure mV value: 3.2.1.Press key, change the meter to mV mode. 3.2.2.Connect ORP electrode or ion electrode (need extra equip) insert it into sample solution, still it after slightly stirring, and reading until there shows stable ORP value or the potential of ion electrode 3.3. Considerations: 3.3.1.Calibration times for meter rely on the sample, electrode performance and required accuracy. For high accurate measurement (d"0.02pH), which should be calibrated immediately with standard buffer solution, for general accuracy measuring (d"0.1pH), which can be used almost one week or long time once be calibrated. However, the meter must be renew calibration read as follows: (a) New electrode and unused one for a long time; (b) After measuring acid (pH<2) or alkaline (pH>12) solution; (c) After measuring solution which contains fluoride and concentrated organic solution; (d) The temperature of solution is much different with calibration temperature. 3.3.2.There are some soak solution in the protect bottle in the front of electrode, the electrode head soak into it for keep the glass bulb and junctions activation. When measuring twist off the cap and expose the electrode, wash it clean with pure water. After using, insert the electrode in and twist the cap on. Once found there are some thickness or go moldy in the protect bottle, then the soak solution should be replaced immediately. 3.3.3.Preparation of the electrode soak solution: Take 25g analytical pure KCL, which need be dissolved in 100ml pure water stir till dissolved completely. The electrode should be avoid soaking into the pure water, protein solution and acid fluoride solution for a long time, and protect it touches with organic silicon lipid. 3.3.4.When the meter calibrating use pH standard buffer solution, in order to improve the measuring accuracy, the pH value of buffer solution should be reliable. The buffer solution should be replaced in time after being used for many times. 3.3.5.Keeping electrode clean and dry, especially note that keep meter and connectors high clean and dry, otherwise, which will lead the electrode inaccuracy or invalidation. If the electrode is dirty which could be cleaned with cotton and alcohol, then blow it try. 3.3.6.The sensitive glass bulb in the front of combination electrode which can not touch with hard things, any broken and hair will make the electrode invalidity. Before and after measuring, the electrode should be washed with pure water and after washing should dry the electrode out and user should not polish the bulb with paper for that will lead potential of electrode is unstable and lengthen response time. The electrode should be washed again and again for remove the sample stuck on the electrode, after measuring sticky sample. 3.3.7.An electrode which be used for a long time, or measured solution that contains a polluting solute easily for the sensitive bubble, or a substance resulting in jam at the junction, the electrode will be getting passivation, its sensitivity grade will decrease and its response is getting slow, the reading are not correct. It could adopt the following method for various cases: (a) The glass bubble which is contaminated and aging: put the electrode into a 0.1mol/L dilute hydrochloric acid (preparation: 9ml hydrochloric acid is diluted into 1000ml.) for 24 hours. Rinse it with pure water, then dipped it into the electrode dipping solution for 24 hours. If it is serious passivation, put the end of electrode into 4% HF(hydrofluoric acid)for 3 or 5 seconds, rinsing it with pure water, then dipped it in the electrode dipping solution for 24 hours to make it renew. (b) Clean for contaminated glass bubble and junction: (For reference) Contamination abluent Inorganic metal oxide dilute acid (<1mol/L) Organic Lipidic dilute washing Resinic macromolecules dilute alcohol, acetone, ether Proteinic haematocyte sediment acidic enzymatic solution (such as dried yeast) Kinds of paint dilute bleacher, peroxide The material of the electrode housing is poly-carbonate. Please pay attention while washing, be careful while using tetrachloro-methane, trichloroethylene, tetrahydrofuran. Because these reagents will dissolve poly-carbonate which lead to the electrode invalidation. 3.3.8. pH Electrode using period is about one year, but it will be short if the using condition is bad, or the maintenance is not well. You should replace a new electrode in time when the electrode is aging or invalidation. The microprocessor inside the meter has a function for inspecting electrode slope automatically (detail see 3.1.5 and 3.1.6). If the slope is less than 85%, you should consider performing the electrode activation (detail see 3.7.), or replace a new electrode. 4. Other Functions for Meter:  4.1.! and ! can be switched: Press the button to change  ! to  ! . 4.2.Battery must be replacing when the sign of battery s electric charge shows on the LCD, it means the voltage lower than we using require. 4.3.Meter will power off automatically after 15 minutes in case of being unused. 4.4.Inside of the meter have two series data of pH buffer solution: pH6.86 series is Chinese pH standard buffer solution data: pH4.00, pH6.86 and pH9.18. pH7.00 series is USA pH standard buffer solution data: pH4.00, pH7.00 and pH10.01. In the same series solution, the meter can automatically recognize three kinds of buffer solution. When the user need to change the series of buffer solution, can put the electrode into pH6.86 or pH7.00 buffer solution, press for a few seconds, when the LCD appearssign, then release the button, LCD appears the blinking number: 6.86 or 7.00,at the moment quickly press increase button or decrease button , can change the buffer solution series. When the number become still it means has already finished the adjustment to the pH buffer solution. This meter before selling out the company the pH buffer solution series is the pH6.86 series, if no necessary, please do not adjust freely, in case of using wrong buffer solution can lead the calibration of the meter wrong, during the using process, if find the error is big difference, please check the pH buffer solution is all right first. 4.5.The meter might be locked occasionally (it cant be closed by press switch button), then the user just need to take out battery and replaced it to battery compartment will be working. 5. Adaptation kit for the meter:  5.1. PHB-4 portable pH meter 5.2. 201B-S plastic pH/ATC 3-in-1 combination electrode 5.3. pH4.00, 7.00, 10.01 buffer solution 1 bottle for each (50ml) 5.4. Model 6F22 9V cell 5.5. Carrying case 5.6. Instruction manual 6. Optional Purchased Accessories:  6.1. 201B-S plastic pH/ATC 3-in-1 combination electrode 6.2. 301Pt-S plastic ORP combination electrode 6.3. pH calibration buffer solution (pH4.00, pH7.00, pH10.01 three kinds) Specs: 50ml/bottle, 250ml/bottle and 500ml/bottle 6.4. pH and ORP electrode soaking solution Specs: 50ml/bottle, 250ml/bottle and 500ml/bottle 7. Warranty:  7.1. This instrument can be free of repairing in parts of products for one year from date of shipment. 7.2. The attached pH electrode is not belong to this warranty range, besides the new one. 7.3. The above warranty will not suitable for error operation by customers. 7.4. The sender is responsible for delivery charges, freight, insurance and proper packaging to prevent damage during transit.  Shanghai San-Xin Instrumentation, Inc. Add: 3/F. Building No.4, No. 471 Guiping Road, Shanghai, China. 200233 Tel: +86-21-63362480 Fax: +86-21-64956880 Website:  HYPERLINK "http://www.shsan-xin.com" www.shsan-xin.com E-mail: wxmab@shsan-xin.com     PAGE  PAGE 9 PHB-4 Version 2.0  DATE \@ "yyyy-M-d" 2009-5-26 1 set 1 pc 1 pc 1 pc 1 book          "$579=?Ahijknyj_ZTZTZTZTZTy CJaJo(CJaJ5OJPJ\aJo(jCJUaJmHnHu5CJ\aJ5CJ\aJo(CJ0OJPJ\aJ0o(5CJ,PJ\aJ5CJ,PJaJ,o(5CJ,PJ\aJ0o(5CJ,PJ\aJ0o(5CJ,PJ\aJ0o(CJ,o( CJ,aJ,o(5CJ0PJ\o(CJ,OJPJ\o(5OJPJ\o(j5OJPJU\o( "#$56789:;<=>?@Ahijk $7$8$H$a$$a$$a$BVCCpqrsUV./@FM* + A B V z {   0 2 <  h r p r t z ͮ CJPJaJ5OJPJ\aJo()j5OJPJU\aJmHnHo(u5CJPJ\aJ5CJPJ\aJo(CJPJaJo(CJOJPJQJaJo(CJaJ5CJ\aJ CJaJo(=A| 4 j r t  Z >~WD` WD` WDd`^ d WDd`Hd VDWDc^`H d VD^  X d v x ,.0Hlnvz|4@(*,68:>JLfhjrʓCJEHPJaJ jCJPJUaJmHnHu)j5OJPJU\aJmHnHo(u5CJ\aJ5CJ\aJo(5CJPJ\aJo(OJPJaJo(CJaJCJH*PJaJ CJPJaJCJPJaJo( CJaJo(668:fj/ja!/3VD ^3 {VDWD^{` VDWD^` VDWD^` VDWD^` VDWD#^`WD`WDd`$da$ IVDWD8^I`WDd`TV-./06_h TUsvhjlxпܳܞ܍܄o^ j˟CJEHOJPJUaJo()jyB*CJEHOJPJUaJo(ph5CJ\aJo( j}CJEHOJPJUaJo()j6lB*CJEHOJPJUaJo(phCJEHOJPJaJo( jCJPJUaJmHnHu@CJOJPJaJo( CJaJo(CJaJCJPJaJo(CJOJPJaJo( CJPJaJ$12gh`agoz!>IJUt*-./5CDTV?!Y!Z!_!֊slsa5CJPJ\aJo( CJPJaJ@CJOJPJQJaJo(@CJPJaJ@CJPJaJo( 5CJaJ5CJaJo(CJaJ jCJEHOJPJUaJo()jB*CJEHOJPJUaJo(ph5CJ\aJo(CJPJaJo( jCJPJUaJmHnHuCJOJPJaJo( CJaJo(&/DZ!q!!x""%.&l&&'(* +,/./112 0dlWD`0 VD WD^`0WD`0 VDWD#^`WD`WDd`HVD^HWDd`_!p!q!r!x!}!!!!!!!!!!!!!3"8"w"x"|""""$$L$b$$$$$%%%&& &-&2&k&p&&&&&''9''((ǽеЪее׵ץ׵ׇץץׇץ׵ץ׵׵ץ׵׵ץ׵CJOJQJaJo(5CJ\aJo(5CJPJ\aJo(CJaJ5CJPJ\aJo(CJPJaJo(CJEHPJaJo(CJEHPJaJ CJPJaJ CJaJo( jCJPJUaJmHnHuCJPJaJo(5CJPJ\aJ5())***++]+^+++,,,,..5.K.O.L/S///////0011111111122_4f4i45555&6J666666666ͯ jCJPJUaJmHnHu5OJPJQJ\aJo()j5OJPJU\aJmHnHo(u5CJ\aJo(5CJPJ\aJo( CJPJaJB*CJPJaJo(phCJPJaJo(CJaJ CJaJo(92K2223T3_4666Z7:888%9/VD ^/WDd` HVDWDc^`H HVDWD$^`H ZVDWD8^`ZdlVDWD#^` dlVD^ HdlWD,`Hdl 0dlWD`0 dlWDd`6"7.7B7D7F7H7P7R7T7V7X7b77798>8888888889 9 99999%9'9F9Z9\9^9d9f9n9q9x9z9k:r:::;;;;<<=2=3=====5CJPJ\aJo(CJPJ\aJo(%jB*CJEHPJUaJo(ph jCJPJUaJmHnHu CJPJaJCJaJ5CJ\aJo(5CJ\aJCJPJaJo( CJaJo(<%9x9;======6>>>>>>>>>)?X???HWD,`HWDd` WDd^` HVDWDc^`HVD^ gVDWD ^g`/VD ^/=======>5>;>A>m>>>>>>>>>>>>>>>>>(?.?W?]?_?}???????????1@3@5@üöüöööööööüüüüööövCJOJPJaJo(OJPJaJo(#jOJPJUaJmHnHo(u5CJ\aJo(5CJPJ\aJo(CJPJaJo( CJaJo( CJPJaJCJPJaJo(5OJPJ\aJo()j5OJPJU\aJmHnHo(u'jCJOJPJUaJmHnHo(u.??1@2@3@@@B@@AOAAAAAAAAAAAAAAA^ HVDWDc^`H VDdWDJ^`HWD,`HWDd`5@?@@@A@B@G@f@@@AANATAAAAABB^B_BBBBBBBBBBBBCCCCCC C Cþɩqllll jU0J5B*CJ\aJo(phjQ5CJU\aJj5CJU\aJaJo(5CJ\aJ)j5OJPJU\aJmHnHo(uCJaJ CJaJo(CJPJaJo(OJPJaJo(#jOJPJUaJmHnHo(u5CJPJ\aJo(5CJ\aJo('AAAAAAAAAAAAAAAAAAAAAAB_BBBCCC^CCCC C CCCC!CTCUCVCWC]CbCcChCmCtCvCwCxCyC{C|C~C$a$$h]ha$h]h&`#$ C CCCCCCCCC C!C3C4CHCICRCSCTCWCcCdChCiCuCvCyCzC|C}CCCCCCCCCCCCCCCCC j`EH U jZEH U jSEH U j^CEH U j/EH U jjEH U jEH U jvEH U jEH UCJPJaJo( CJPJaJ CJaJo( mHnHu jUo(0JmHnHu0J j0JU-~CCCCCCCCCCCCCCCCCCCCC^$a$7 0&P 182P. 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